Synergetic Improvement of Flexoelectric Coefficient in liquid Crystal Embedded Flexible PVDF Polymer Composite for Energy Harvesting Applications.

Flexoelectricity is the universal electric polarization of dielectrics upon exertion of a non-uniform strain gradient. With the advancement of nano-technology and miniaturization of electronic devices, flexoelectricity holds the promise to address the power requirements for such device operation. The direct flexoelectric effect in liquid crystal (LC) embedded Poly(vinylidene fluoride) (PVDF) polymer films is examined for the first time by the application of external strain on the films. Physical characterizations such as DSC, dielectric spectroscopy, XRD and FESEM are carried out to study the composite films' intrinsic and extrinsic properties like dielectric, crystallinity and morphologies. The value of the flexoelectric coefficient (µ12) increases with the concentration of LC incorporation. At 3wt%, µ12 attains a maximum value of 68 nC/m, which is more than a three-fold increase compared to that of the pure PVDF film. The role of Maxwell Wagner Sillars (MWS) polarization in determining flexoelectric polarization in polymer composites is also discussed. Moreover, the influence of the microstructure and domain size formation in determining the flexoelectric response are discussed in detail to infer the behaviour of the flexoelectric coefficients of the films. Potential device applications based on this phenomenon have been proposed for future research in sensing and actuation. This article is protected by copyright. All rights reserved.

Nanoscale surface metrology with a liquid crystal-based phase-shifting angular shearing interferometer.

In this Letter, a phase-shifting angular shearing interferometer has been proposed for the application in optical surface metrology (SM) by using a combination of a wedge-shaped liquid crystal (LC) cell and a polarization phase shifter. The demonstration of this angular shearing interferometer for step height measurement is accomplished with the help of a phase-shifting technique. Four phase-shifted interferograms produced by a geometrical phase shifter are subjected to a simplified Wiener deconvolution method, which resembles a simple analysis technique for shearing interferograms in comparison to alternative approaches. A simulation study has been conducted to validate the proposed technique. The experimental results show an accuracy of 5.56% for determining the step height, which also agrees with the results obtained by atomic force microscopy. Owing to the tunability of birefringence, the proposed LC-based angular shearing interferometry technique will be useful to control spatial resolution in optical metrology.

Effect of CdSe/ZnS quantum dot dispersion on phase transitional behavior of 8OCB liquid crystal.

We report the effect on the phase transitional behavior of 8OCB liquid crystal (LC) doped with functionalized CdSe/ZnS quantum dots (QDs) in different concentrations. The temperature-dependent data of high-resolution optical birefringence and dielectric anisotropy are utilized to characterize the critical anomaly for both the isotropic-to-nematic (I-N) and nematic-to-smectic-A (N-SmA) phase transitions. The obtained results reveal that the order parameter exponent (ß) for the pure LC is found to be ß=0.249 and does not vary upon the inclusion of QDs in the pure matrix. It describes the weakly first-order characteristic of the I-N phase transition for all the studied samples, which falls within the limit of the tricritical hypothesis. Conversely, depending on the range of the N phase, we observed a nonuniversal nature of the specific heat capacity critical exponent (α^{'}) linked with the N-SmA phase transition for all the studied samples. A relative comparison was made amongst the α^{'} values extracted from both the anisotropy data, and further, a theoretical relationship is established with these exponent values. The coupling strength among the N and SmA order parameters is determined using the optical birefringence data and discussed from the perspective of mutual interaction between the LC-QDs ligands. The results signify that a strong ligand-ligand interaction between neighboring QDs effectively reduces the N range and slightly influences the N-SmA phase transition.

Electrically controlled dual-mode polarization beam splitter using a nematic liquid crystal.

Polarization handling using an external source is highly desirable in applied optics and photonics to increase the degree of freedom of an optical system. Here we report an electrically controlled polarization beam splitter (PBS) by sandwiching the nematic liquid crystal (LC) between two equilateral prisms. The presented LC-PBS is operated in two different modes: non-splitting mode and polarization splitting mode. The externally applied voltage can switch the mode of the PBS, which makes the device active and flexible. The proposed electrically controlled PBS exhibits features such as bistability with highly stable modes, large splitting angle, wider operating range, and ease of fabrication with lower cost.

Liquid crystal based polarized low coherence interferometer for optical demodulation in sensors.

The resolution of the measurement detection and sensitivity of a polarized low coherence interferometer (PLCI) can be pre-engineered by optimizing the key parameters of the birefringent wedge, which is rarely reported. In this work, we introduce a liquid crystal (LC) wedge in the PLCI and use it to demodulate Fabry-Perot (FP) cavity length. The birefringence property of the nematic LC is used to convert the optical path difference (OPD) of the sensor into a spatial distribution. This results in the production of localized interference fringe patterns. The formation of PLCI fringes and the related shift of the interferogram with a variation in the displacement of the FP displacement sensor is explained with reference to the OPD matching between an LC wedge and the FP cavity. The displacement value is demodulated from the obtained fringe pattern by tracking the centroid position of the fringe envelope and also considering the birefringence dispersion. An additional simulation study shows that the spatial position of the interferogram signal coupled with the dispersion coefficient is almost identical to the experimental data. The demodulated results from both the simulation and experimental investigations are found to be consistent with each other and closely agree with the actual cavity length. Further, the possibility to enhance the sensing resolution is examined by modulating the interferogram fringes using an electric field. Compared to birefringent crystals, the LC wedge presented here is found to be advantageous for high precision and tunability of the measurement range, which is useful for robust fiber optic sensing applications.

Liquid crystal droplet design by using pseudopeptidic bottlebrush polymer additives.

Liquid crystal (LC) droplets are promising candidates for sensing applications due to their high sensitivity to surface anchoring changes, resulting in readily detectable optical effects. Herein, we have designed and synthesized amino acid-based bottlebrush polymers and investigated their impact on LC director configurations in the droplets. The pseudopeptidic bottlebrush polymers with an aromatic (phenyl) and aliphatic appendages are synthesized using ring-opening metathesis polymerization (ROMP). Polymer dispersed liquid crystal (PDLC) samples are prepared by employing pseudopeptidic bottlebrush polymers and 4-cyano-4'-pentylbiphenyl (5CB) LC via solvent-induced phase separation (SIPS) technique. Due to π-π stacking, the phenyl group favours radial configuration, whereas the repulsion between 5CB and aliphatic groups induces molecular alignment leading to bipolar droplet arrangement. The impact of various pendant groups attached to the polymer on the prepared PDLC sample's surface characteristics and free energy components is illustrated. The sensing capability of 5CB dispersed in pseudopeptidic bottlebrush polymers for various pH solutions is investigated using polarizing optical microscopy (POM). The PDLC samples are moderately permeable to water and sensitive to different pH solutions. The results demonstrate a simplified and straightforward approach for preparing LC-based biosensors and chemical sensors.

Determination of refractive indices for liquid crystals using a double transmission technique.

We report a new, to the best of our knowledge, approach to determine the refractive indices (RIs) of liquid crystal (LC) systems by considering a double transmission phenomenon of a light beam within the LC medium and the principle of the wedged-cell refractometer. This modified system delivers better spatial resolution of refracted beams in terms of well-resolved spots, compared to the single transmission of a beam in the conventional thin-prism method. The deviation angle obtained in this method is found to be comparatively greater than that of the thin-prism method. The higher values of deviation angle are described using a theoretical model and further experimentally demonstrated for the 5CB nematic LC compound. The variation of the principal RIs (no, ne), and hence the birefringence (Δn) with temperature as well as electric field is investigated for both transmission methods. A relative comparison is carried out between the simulated and standard values obtained from literature. The present technique provides a higher spatial beam resolution to determine the RIs and birefringence of LC systems, which can be very advantageous for different modern photonic applications based on beam shaping and steering.

Nematic twist-bend phase of a bent liquid crystal dimer: field-induced deformations of the helical structure and macroscopic polarization.

The twist-bend nematic (Ntb) phase is a recent addition to the family of nematic (N) phases of liquid crystals (LCs). A net polar order in the Ntbphase under an external electric field is interesting and it was predicted in several recent theoretical studies. We investigated the field-induced polarization behaviour, dielectric, and electro-optic properties of a bent LC dimer CB7CB in the N and Ntbphases. A threshold-dependent polarization current response was obtained in both the phases under triangular and square-wave input electric fields, existing till frequencies as high as 150 Hz. The polarization switching times were found in ∼1 ms region, especially in the N phase. In the Ntbphase, electric field-induced deformation of the helical structure was observed, like ferroelectric LCs. Dielectric measurements revealed the presence of cybotactic clusters via collective relaxations. The dielectric anisotropy (Δϵ) is negative at the frequencies of polarization measurements. The net polarization resulted from field-induced reorientation of cybotactic clusters and additionally from the field-induced deformation of helical structures in the Ntbphase. We explored the possibility of ionic contributions to the net polarization by synthesizing TiO2nanoparticles (NPs) dispersed CB7CB LC nanocomposite. Incorporation of the NPs resulted in reduction of the collective order, increase in the ionic impurity content and conductivity, but an extinction of the field-induced polarization response. Our results demonstrate that the net polarization has competing contributions from both ferroelectric-like and ionic origin (up to ∼10 Hz) in the LC phases, but it becomes dominantly ferroelectric-like at higher frequencies.

Hydrophobicity Directed Chiral Self-Assembly and Aggregation-Induced Emission: Diacetylene-Cored Pseudopeptide Chiral Dopants.

Here we delineate simple and tunable hydrophobically driven chiral functional assemblies of diacetylene cored pseudopeptides. These amino acid appended, rigid core dialkynes constitute promising chiral supramolecular building blocks for materials properties engineering. The chiral appended amino acid elements allow for simple tuning of solubility and interaction properties as well as governing chirality, while the central dialkyne core can impart hydrophobically driven assembly and Aggregation Induced Emission (AIE) properties. The self-assembly of these rod-like dialkynes can be regulated by tuning the solvent environment, with for example self-assembly into vesicles in acetonitrile and into helical organization with AIE in a H2 O/DMSO mixture. Of additional high interest, these supramolecular materials, themselves devoid of liquid crystal (LC) properties, can induce chirality into non-chiral LC matrices with high helical twisting power.

Designer Peptide-PVDF Composite Films for High-Performance Energy Harvesting.

Polymers and peptides have recently been considered as promising materials for piezoelectric energy harvesting because of their biocompatibility and enormous design possibility. However, achieving significant output voltages while meeting environmental safety requirements, low cost, and easy fabrication remains a major challenge. Herein, lipidated pseudopeptide incorporated poly(vinylidene fluoride) (PVDF) composite films are fabricated. Adding lipidated pseudopeptide (BLHA) increases the electroactive phase content, reaching the maximum for the 2 wt% composite film. The composite film containing 2 wt% BLHA manifests the highest dielectric constant and remnant polarization (Pr ), among others. A piezoelectric energy harvesting device fabricated with this film generates open-circuit output voltages up to 23 V, five times amplified output compared to pure PVDF. To the best of our knowledge, this material is superior among the peptide-based piezoelectric energy harvesters reported in the literature. The device is flexible, durable, low cost, and sensitive to high and low pressures. It can power up multiple liquid crystal display panels when pressed with a finger. The non-covalent interaction between BLHA and PVDF is the reason behind the composites' improved piezoelectric response. Density functional theory calculations also support this notion.

Quantum-dots-dispersed bent-core nematic liquid crystal and cybotactic clusters: Experimental and theoretical insights.

We study a quantum-dots (QDs) dispersed bent-core nematic liquid crystalline system in planar geometry and present experimental measurements of the birefringence (Δn), order parameter (S), dielectric dispersion, absorption spectra, and optical textures with attention to variations with temperature. A bent-core liquid crystal (LC) 14-2M-CH_{3} is used as the host material and CdSe/ZnS core-shell type QDs are used as the dopant. The nematic (N) phase of the pristine (undoped) LC 14-2M-CH_{3} contains cybotactic clusters, which are retained by its QDs incorporated LC nanocomposite. Our experimental findings support: (i) reduced orientational order parameter of the QDs dispersed LC system compared to its pristine counterpart at fixed temperatures, (ii) reduced cybotactic cluster sizes due to the incorporation of QDs, and (iii) increased activation energies related to reduced cluster sizes. We complement the experiments with a novel Landau-de Gennes-type free energy for a doped bent-core LC system that qualitatively captures the doping-induced reduced order parameter and its dependence on the properties of the QDs and its variation with temperature.

One-dimensional theoretical analysis of coupling and confinement effects on the cybotactic clusters of bent-core nematic liquid crystals.

The bent-core liquid crystals (LCs) are highly regarded as the next-generation materials for electro-optic devices. The nematic (N) phase of these LCs possesses highly ordered smecticlike cybotactic clusters which are promising for electro-optic applications. We have studied a one-dimensional Landau-de Gennes model of spatially inhomogeneous order parameters for the N phase of bent-core LCs. We investigate the effects of spatial confinement and coupling (between these clusters and the surrounding LC molecules modeled by a coupling parameter γ) on the order parameters. The coupling is found to increase the cluster order parameter significantly, suggesting enhancement in cluster formation, and also predicts a transition to a phase with weak nematiclike ordering above the nematic supercooling temperature.

Nanodoping: a route for enhancing electro-optic performance of bent core nematic system.

We report the effect of dispersion of barium titanate (BaTiO3) nanoparticles (BNPs) in a four ring bent core nematic (BCN) liquid crystal. Polarizing optical microscopy reveals the presence of a single nematic phase in pure and doped states. Polar switching has been observed in the bent core system and the value of spontaneous polarization (P s) increases with increase in doping concentration of BNPs in BCN. Dielectric study shows a lower frequency mode, which can be ascribed to the formation of cybotactic clusters. These clusters are also responsible for the observed polar switching in pure, as well as, in doped BCNs. Another higher frequency mode, observed only in pure BCN, indicates the rotation of molecules about their long molecular axis. The conductivity of doped samples is also found to decrease as compared to the pure BCN. This reduction helps in the minimization of negative effects caused by free ions in liquid crystal based devices. This study demonstrates that the interaction between BNPs and BCN molecules improves the P s, dielectric behaviour, viscosity and reduces the conductivity of pure BCN. Hence, nanodoping in a BCN is an effective method for the enhancement of electro-optic performances and will lead to the development of faster electro-optic devices.